Radiation InducedPolymerizations of Acrylonitrile-Zinc Chloride Complexes
نویسندگان
چکیده
منابع مشابه
The Structure of Zinc Chloride Complexes in Aqueous Solution
The structure of zinc chloride complexes with different ratios of chloride to zinc, formed in concentrated ZnCl2 aqueous solutions, were determined f rom large-angle X-ray scattering using concentrations of the chloride complexes estimated by complementary Raman spectroscopic measurements. The highest chloro complex, [ZnCl4]~, is tetrahedral with a Zn-Cl bond length of 2.294(4) Ä. The trichloro...
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Under anhydrous conditions and in the absence of a Lewis-base solvent, a zinc chloride complex with tri-tert-butyl-phosphane as the μ-bridged dimer is formed, viz. di-μ-chlorido-bis-[chlorido-bis-(tri-tert-butyl-phosphane)zinc], [ZnCl4(C12H27P)2], (1), which features a nearly square-shaped (ZnCl)2 cyclic core and whose Cl atoms inter-act weakly with C-H groups on the phosphane ligand. In the pr...
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The monomer, acrylonitrile, was graft copolymerized onto kappa-carrageenan (kC) using γ-rays as initiator. The reactions were carried out in a homogenous aqueous medium. After removal of the homopolymer, the graft copolymer was characterized by FTIR spectroscopy. A plausible mechanism of grafting has also been suggested. The effect of various factors affecting on grafting, i.e. dose of δ-rays a...
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Thermal decomposition of layered zinc hydroxide double salts provides an interesting alternative synthesis for particles of zinc oxide. Here, we examine the sequence of changes occurring as zinc hydroxide chloride monohydrate (Zn5(OH)8Cl2·H2O) is converted to crystalline ZnO by thermal decomposition. The specific surface area of the resultant ZnO measured by BET was 1.3 m(2) g(-1). A complicati...
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Zinc can be inserted into the carbahemiporphyrazines by use of the organometallic reagent diethylzinc; in the case of benziphthalocyanine, concomitant alkylation of an alpha-carbon position and metalation occurs.
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1964
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.67.10_1658